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<span class="sp1">CASE</span> </a> <a class="bigBtn" href="/about/qiyeshili/"> <img src="/template/pc/skin/images/icon3.png" alt="企業實力"><br> 企業實力<br> <span class="sp1"></span> </a> </div> <div class="subR news"> <div class="title"> <h1><img src="/template/pc/skin/images/iconsubr.png" alt="">橋梁漆 </h1> </div>  <span> > <a href='/' class=''>首頁</a> > <a href='/cpyt/' class=''>產品用途</a> > <a href='/cpyt/qiaoliangqi/'>橋梁漆</a></span> <div class="newsText"> <h1 class="nTitle">鋼結構橋梁防腐體系</h1> <div class="info">作者：小編來源：未知發布時間：2021-06-26 19:38:33</div> <div class="txt"><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">橋梁一直是人類制作出的杰作之一，而我國的橋梁文化也淵源深厚，從遙遠的古代至今，一直都在刷新著世界人民對橋梁的認識，近年來也有著多個創紀錄的各種橋梁，這不僅僅是交通工程，更是一件件珍貴的藝術品，成為了城市標志性景觀。</div><p> </p><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">而橋梁的腐蝕卻一直是業主擔憂的問題，橋梁通常受到的腐蝕中，其主要是大氣腐蝕，不過隨著大氣環境不同，橋梁受到的腐蝕也有差別。而根據橋梁的銹蝕速度，橋梁維護費用也非常高昂。</div><p> </p><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">橋梁防腐分為鋼結構部分和混泥土部分。今天我們講一講鋼結構橋梁的防腐涂料都有哪些。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">一、底漆</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">現代化橋梁鋼結構主體基本上采用屬電化學保護類型的底涂層，如富鋅底涂層和熱噴涂金屬底涂層。富鋅底涂層分為環氧富鋅底漆和無機富鋅底漆，而無機富鋅底漆又分為醇溶型無機富鋅底漆和水性無機富鋅底漆。電化學保護類底涂層依靠電化學保護機理保護鋼鐵基材，避免銹蝕發生</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">這幾類電化學保護底涂層的特點比較如下：</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">(1) 環氧富鋅涂料對表面處理及施工環境的要求相對寬松，涂料涂層的力學性能好，具有良好的電化學保護性能，但濕度高不適用，高溫高濕和低溫高濕環境更不適用。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">(2) 醇溶型無機富鋅涂料與水性無機富鋅涂料對表面處理、施工環境要求較高，在嚴格控制施工質量的前提下，可獲得比環氧富鋅更好的防腐性能，同時具有優良的耐介質腐蝕性能和耐溫性能。醇溶型無機富鋅底漆需要在較高濕度(≥60%)下、較長時間(1 ~3 d)內完成固化；水性無機富鋅涂料對表面處理要求極高，清潔度需達到Sa3 級，濕度較高的涂裝環境對涂膜固化不利。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">(3) 熱噴金屬涂層電化學保護性能優異，與長效型涂層體系配套構成最長效的防腐體系。但熱噴金屬涂層對表面處理的要求嚴格，并且熱噴金屬涂層還存在環境污染、職業危害和高耗能等弊端，不符合節能減排的大趨勢。同時，金屬熱噴涂復合涂層的性能很大一部分還取決于封閉涂層及配套涂層的性能及施工工藝，而配套和施工不到位引起的涂料涂層早期失效的現象時有發生。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">上述3 類底漆在現代化橋梁建設中均有使用。目前，鐵路橋梁基本上采用環氧富鋅底漆，如武漢天興洲大橋、南京大勝關大橋等，只有少量采用水性無機富鋅底漆。對于公路橋梁，環氧富鋅底漆、醇溶型無機富鋅底漆及熱噴金屬涂層均有采用，也有少量采用水性無機富鋅底漆。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">對于富鋅涂料有以下幾點說明：</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">(1) 無機富鋅涂料由于孔隙度大，直接噴涂厚漿型環氧云鐵中間漆容易產生針孔等涂層缺陷，所以一般要采用過渡型封閉底漆。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">(2) 經典的醇溶型無機富鋅底漆施工后，漆膜干燥很快，表觀上漆膜已經固化，但是涂膜的完全固化需要在相對濕度大于60%的環境下，養護 1 ~ 3 d 才能完成。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">(3) 干膜中鋅粉含量和干膜中金屬鋅含量的區別。干膜中鋅粉含量是配方設計值，是鋅粉含量與涂料所有成膜組分質量的比值；不揮發分中金屬鋅含量是試驗值，是指配方中單質金屬鋅與涂料不揮發分的比值。不揮發分中金屬鋅含量與鋅粉的純度和實驗誤差有關。通常情況下，環氧富鋅涂料干膜中鋅粉含量大于80%時，干膜中金屬鋅含量才能達到70%。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">(4) 鱗片狀富鋅底漆的鋅粉含量要求。采用鱗片狀鋅粉制備的富鋅底漆比一般純球型鋅粉制備的富鋅底漆鋅粉含量要低，一般規定：純鱗片狀鋅粉的不揮發分中金屬鋅含量≥40%，球/片結合型的不揮發分中金屬鋅含量≥60%。雖然鱗片狀富鋅底漆鋅粉含量大大降低，但漆膜的電流導通性大大加強(漆膜表面電阻率≤1 × 10?5 Ω)。這是由于涂膜中鱗片狀鋅粉的面接觸代替了球狀鋅粉的點接觸所致，過高的鱗片狀鋅粉含量反而使片狀鋅粉難以平行搭接，孔隙度增大，防腐性能下降。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">除了電化學保護底漆外，還有一類鈍化緩蝕型底漆。鐵路橋上普遍采用醇酸紅丹防銹底漆，但由于紅丹防銹漆對人體有極大的危害，在歐美已被禁用。我國2009 年制訂的《石油和化工產業結構調整指導意見》中明確指出，要加快淘汰紅丹防銹漆。為適應環保和職業健康要求，JT/T 722 推薦了環保型的鈍化緩蝕型環氧磷酸鋅防腐底漆。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"></div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">二、中間漆</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">目前，橋梁用中間涂層基本上都是環氧云鐵中間漆。片狀云母氧化鐵延長了腐蝕介質的滲透路徑，提高了涂層的屏蔽效果，并且片狀結構填料吸收內應力，增強了涂層的力學性能。與成膜環氧樹脂優異的力學性能和防腐性能相匹配形成的環氧云鐵中間漆，是目前最常用的長效型防腐涂層體系中間涂層。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">市場上的環氧云鐵中間漆有幾個類型：按涂裝厚度可分為薄涂型和厚涂型，薄涂型一道40 ~ 60 μm，厚涂型一道100 ~150 μm；按云鐵灰的加入量和制備工藝可分為兩大類，一類以云鐵灰為主要填料，復配少量的鋁粉、硫酸鋇等填料攪拌而成；另一類是選擇其他顏填料研磨至規定細度后，再加入云鐵灰攪拌而成。環氧云鐵的質量與固化劑的品質，云鐵灰、鋁粉的含量和片狀結構以及顏填料的分散性有關。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">三、面漆</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">當前國內橋梁鋼結構主體工程基本上采用高耐候性面漆。由于氯化橡膠在生產過程中污染環境，國外已逐步淘汰。雖然丙烯酸面漆單組分施工方便，但固體含量低、VOC 含量高，不符合國家環保政策導向。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">上述兩種涂料在現代橋梁鋼結構防腐中很少使用?，F代化橋梁面漆主要采用丙烯酸聚氨酯面漆，但國內橋梁逐步采用耐候性更加突出的FEVE 氟碳面漆代替丙烯酸聚氨酯面漆。大型鐵路橋梁的主體結構基本上采用氟碳涂層，有少部分采用灰鋁粉石墨醇酸面漆。而大型公路橋梁氟碳漆也占到接近一半的市場份額，并有擴大的趨勢。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">國內也有少部分公路橋梁采用耐候性同樣突出、更加環保的聚硅氧烷面漆。雖然氟碳面漆的應用在逐步擴大，但并不是說丙烯酸聚氨酯涂料已經過時，質量優良的丙烯酸聚氨酯涂料也可以維持15 年甚至20 年以上的使用壽命，國外有很多這樣的實例。實際上，歐美國家還在普遍采用丙烯酸聚氨酯涂料。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">常溫固化FEVE 氟碳涂料用樹脂是由三氟氯乙烯或四氟乙烯與乙烯基醚或乙烯基酯單體共聚而成，并復配帶羥基和羧基的乙烯基功能單體。按照單體共聚的類型，目前國內市場化的FEVE 產品包括3 類：三氟氯乙烯–醋酸乙烯酯共聚物、四氟乙烯–乙烯基醚共聚物、三氟氯乙烯–乙烯基醚共聚物。目前，由于價格問題和市場競爭的不規范，導致三氟氯乙烯–醋酸乙烯酯類型用量最大，四氟乙烯–乙烯基醚也有一定的市場，三氟氯乙烯–乙烯基醚的用量較少。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">工程聚硅氧烷涂料采用有機改性聚硅氧烷樹脂作為成膜物，結構上的顯著特點是有機–無機混接雜化，有機硅成分最少在50%以上，最好的達到70%。以有機硅成分為主體保證其耐候性，拼入一定的丙烯酸或環氧改性樹脂以提高其成膜性能和力學性能。工程聚硅氧烷涂料分為環氧聚硅氧烷和丙烯酸聚硅氧烷兩大類。聚硅氧烷涂料為外資企業所壟斷，在橋梁領域有少量應用，它的最大優勢是環保，但是施工環境、施工工藝條件對其涂膜質量的影響較大，使其使用受到一定的限制。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">幾類耐候面漆的綜合性能比較見表3。乙烯基醚型FEVE 氟碳樹脂具有最優異的耐候性能，丙烯酸聚硅氧烷的耐候性與醋酸乙烯酯型FEVE的耐候性相當，而環氧聚硅氧烷的耐候性稍微差一些，但也明顯好于丙烯酸聚氨酯面漆。從防腐蝕性能上考察，環氧聚硅氧烷和乙烯基醚型FEVE 樹脂最優，而丙烯酸聚硅氧烷和醋酸乙烯酯型FEVE 要稍弱一些。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;">從施工工藝性能上，丙烯酸聚氨酯最優，聚硅氧烷涂料對施工環境的敏感性較高。聚硅氧烷涂料最大的施工優點是厚膜施工，但現代化橋梁一般需要2 道施工；因此，它在這方面的施工優越性無法體現。從環保性能方面考慮，聚硅氧烷涂料以高的體積固含量、不含異氰酸酯固化劑而具有明顯的環保優勢。</div><div style="font-family: 微軟雅黑; font-size: 14px; white-space: normal;"> </div><p><br/></p></div>   <div class="neighboring"> <img 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